SDS_ASOPLAST-MZ_-_202222_(13)EN.pdf
8 Pages
204 KB
Download
<h1>SDS_ASOPLAST-MZ_-_202222_(13)EN.pdf</h1> <p>60.0.21</p> <p>Page 1/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 31.01.2025</p> <p>Version number 13 (replaces version 12)</p> <p>Revision: 31.01.2025</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ASOPLAST-MZ <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Dispersion <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Detmold, Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />Internet: www.schomburg.de <br />· Informing department: <br />Department: Environment and Safety <br />************************************ <br />If you have any questions about the Environment and Safety Department, please contact our <br />department. <br />e-mail: SDB@schomburg.de <br />· 1.4 Emergency telephone number: <br />Poison centre Berlin (24 hours) <br />German & English <br />Tel: ++49 (0)30/30686700 <br />*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />The product is not classified, according to the GB CLP regulation. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 Void <br />· Hazard pictograms Void <br />· Signal word Void <br />· Hazard statements Void <br />· Additional information: <br />EUH208 Contains reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and <br />2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1), 1,2-benzisothiazol-3(2H)-one. May <br />produce an allergic reaction. <br />EUH210 Safety data sheet available on request. <br />· 2.3 Other hazards Not anwendbar. <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />GB</p> <p>(Contd. on page 2)</p> <p>60.0.21</p> <p>Page 2/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 31.01.2025</p> <p>Version number 13 (replaces version 12)</p> <p>Revision: 31.01.2025</p> <p>Trade name: ASOPLAST-MZ <br />(Contd. of page 1)</p> <p>*</p> <p>SECTION 3: Composition/information on ingredients <br />· 3.2 Mixtures <br />· Description: Water-based Polymer-Dispersion. <br />· Dangerous components: <br />CAS: 2634-33-5 <br />1,2-benzisothiazol-3(2H)-one <br /><0.005% <br />EINECS: 220-120-9 <br />Acute Tox. 2, H330; <br />Eye Dam. 1, H318; <br />Aquatic <br />Index number: 613-088-00-6 Acute 1, H400; <br />Acute Tox. 4, H302; Skin Irrit. 2, H315; <br />Skin Sens. 1, H317 <br />ATE: LD50 oral: 450 mg/kg <br />LC50/4 h inhalative: 0.21 mg/l <br />Specific concentration limit: Skin Sens. 1A; H317: C ≥ 0.036 <br />% <br />CAS: 55965-84-9 <br />reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC <0.0015% <br />Index number: 613-167-00-5 no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. <br />220-239-6] (3:1) <br />Acute Tox. 3, H301; Acute Tox. 2, H310; Acute Tox. 2, <br />Skin Corr. 1C, H314; Eye Dam. 1, H318; <br />H330; <br />Aquatic Acute 1, H400 (M=100); Aquatic Chronic 1, <br />H410 (M=100); <br />Skin Sens. 1A, H317, EUH071 <br />Specific concentration limits: Skin Corr. 1C; H314: C ≥ 0.6 <br />% <br />Skin Irrit. 2; H315: 0.06 % ≤ C <br />< 0.6 % <br />Eye Dam. 1; H318: C ≥ 0.6 % <br />Eye Irrit. 2; H319: 0.06 % ≤ C <br />< 0.6 % <br />Skin Sens. 1A; H317: C ≥ <br />0.0015 % <br />· Additional information For the wording of the listed hazard phrases refer to section 16. <br />SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />Take up a doctor immediately! <br />· After inhalation Supply fresh air or oxygen; call for doctor. <br />· After eye contact Rinse opened eye for several minutes under running water. <br />· After swallowing <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Show the packaging or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents Product is inflammable during water-component is existing. <br />(Contd. on page 3) <br />GB</p> <p>60.0.21</p> <p>Page 3/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 31.01.2025</p> <p>Version number 13 (replaces version 12)</p> <p>Revision: 31.01.2025</p> <p>Trade name: ASOPLAST-MZ <br />(Contd. of page 2)</p> <p>· 5.2 Special hazards arising from the substance or mixture <br />No further relevant information available. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Product is inflammable during water-component is existing. <br />Follow the emergency-plan. <br />Burst- and explosion-danger by increasing pressure. <br />In case of fire chill the container with water spray. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Wear protective clothing. <br />Avoid eye- and skin contact. <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: <br />Do not allow product to reach sewage system or water bodies. <br />Inform respective authorities in case product reaches water or sewage system. <br />· 6.3 Methods and material for containment and cleaning up: <br />Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Do not store open containers. <br />Do not keep food in the area of work. <br />Keep out of the reach of children <br />· Information about protection against explosions and fires: No special measures required. <br />· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: Temperature to store: 15 - 35 degrees <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: None. <br />· 7.3 Specific end use(s) No further relevant information available. <br />SECTION 8: Exposure controls/personal protection <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />The product does not contain any relevant quantities of materials with critical values that have to be <br />monitored at the workplace. <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Appropriate engineering controls <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Individual protection measures, such as personal protective equipment <br />· General protective and hygienic measures <br />Wash hands during breaks and at the end of the work. <br />(Contd. on page 4) <br />GB</p> <p>60.0.21</p> <p>Page 4/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 31.01.2025</p> <p>Version number 13 (replaces version 12)</p> <p>Revision: 31.01.2025</p> <p>Trade name: ASOPLAST-MZ <br />(Contd. of page 3)</p> <p>The usual precautionary measures should be adhered to in handling the chemicals. <br />Do not eat, drink or smoke while working. <br />Use skin protection cream for preventive skin protection. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: Not required. <br />· Hand protection <br />In case of wearing synthetic protective gloves use cotton-gloves as underwear. <br />The glove material has to be impermeable and resistant to the product/ the substance/ the <br />preparation. <br />Selection of the glove material on consideration of the penetration times, rates of diffusion and the <br />degradation <br />· Material of gloves <br />Gloves made of: Natural latex, polychloroprene, nitrile rubber. <br />(Chemical protection gloves of category 3, recognisable by the CE mark with four-digit test number). <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Not suitable are gloves made of the following materials: <br />Leather gloves <br />Strong gloves <br />· Eye/face protection Suitable safety goggles in accordance with DIN EN 166. <br />· Body protection: Protective work clothing. <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Physical state <br />Liquid <br />· Colour: <br />White <br />· Smell: <br />Characteristic <br />· Odour threshold: <br />Not determined. <br />· Melting point/freezing point: <br />Not determined <br />· Boiling point or initial boiling point and <br />boiling range <br />>100 °C <br />· Flammability <br />Not applicable. <br />· Lower and upper explosion limit <br />· Lower: <br />Not determined. <br />· Upper: <br />Not determined. <br />· Flash point: <br />Not applicable <br />· Decomposition temperature: <br />Not determined. <br />· pH at 20 °C <br />10 <br />· Viscosity: <br />· Kinematic viscosity <br />Not determined. <br />· dynamic at 20 °C: <br />1,600 mPas (D 1/s = 6,45) <br />· Solubility <br />· Water: <br />miscible <br />· Partition coefficient n-octanol/water (log <br />value) <br />Not determined. <br />· Steam pressure: <br />Not determined. <br />· Density and/or relative density <br />· Density at 20 °C <br />1 g/cm³ <br />· Relative density <br />Not determined. <br />(Contd. on page 5) <br />GB</p> <p>60.0.21</p> <p>Page 5/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 31.01.2025</p> <p>Version number 13 (replaces version 12)</p> <p>Revision: 31.01.2025</p> <p>Trade name: ASOPLAST-MZ <br />(Contd. of page 4)</p> <p>· Vapour density</p> <p>Not determined.</p> <p>· 9.2 Other information <br />· Appearance: <br />· Form: <br />Pasty <br />· Important information on protection of health <br />and environment, and on safety. <br />· Self-inflammability: <br />Product is not selfigniting. <br />· Explosive properties: <br />Product is not explosive. <br />· Solvent separation test <br />· Organic solvents: <br />0.0 % <br />· Change in condition <br />· Evaporation rate <br />Not determined. <br />· Information with regard to physical hazard <br />classes <br />· Explosives <br />· Flammable gases <br />· Aerosols <br />· Oxidising gases <br />· Gases under pressure <br />· Flammable liquids <br />· Flammable solids <br />· Self-reactive substances and mixtures <br />· Pyrophoric liquids <br />· Pyrophoric solids <br />· Self-heating substances and mixtures <br />· Substances and mixtures, which emit <br />flammable gases in contact with water <br />· Oxidising liquids <br />· Oxidising solids <br />· Organic peroxides <br />· Corrosive to metals <br />· Desensitised explosives</p> <p>Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions No dangerous reactions known <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />*</p> <p>SECTION 11: Toxicological information <br />· 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 <br />· Acute toxicity Based on available data, the classification criteria are not met. <br />· LD/LC50 values that are relevant for classification: <br />2634-33-5 1,2-benzisothiazol-3(2H)-one <br />Oral <br />LD50 <br />450 mg/kg (ATE) <br />670 mg/kg (rats) (OECD 401) <br />Dermal LD50 <br />>2,000 mg/kg (rats) (OECD 402) <br />(Contd. on page 6) <br />GB</p> <p>60.0.21</p> <p>Page 6/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 31.01.2025</p> <p>Version number 13 (replaces version 12)</p> <p>Revision: 31.01.2025</p> <p>Trade name: ASOPLAST-MZ <br />(Contd. of page 5)</p> <p>Inhalative LC50/4 h 0.21 mg/l (ATE) <br />55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and <br />2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) <br />Oral <br />LD50 <br />64 mg/kg (rats) <br />Dermal LD50 <br />87.12 mg/kg (Kan) <br />Inhalative LC50/4 h 0.33 mg/l (rats) <br />· Primary irritant effect: No irritant action known. <br />· Skin corrosion/irritation Based on available data, the classification criteria are not met. <br />· Serious eye damage/irritation <br />Light irritate-effect is possible. <br />Irritate-effect is possible. <br />Based on available data, the classification criteria are not met. <br />· Respiratory or skin sensitisation Based on available data, the classification criteria are not met. <br />· Germ cell mutagenicity Based on available data, the classification criteria are not met. <br />· Carcinogenicity Based on available data, the classification criteria are not met. <br />· Reproductive toxicity Based on available data, the classification criteria are not met. <br />· STOT-single exposure Based on available data, the classification criteria are not met. <br />· STOT-repeated exposure Based on available data, the classification criteria are not met. <br />· Aspiration hazard Based on available data, the classification criteria are not met. <br />· 11.2 Information on other hazards <br />· Endocrine disrupting properties <br />None of the ingredients is listed. <br />*</p> <p>SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />2634-33-5 1,2-benzisothiazol-3(2H)-one <br />EC 50 <br />0.11 mg/kg /72h (Selenastrum capricornutum) (OECD 201) <br />LC50/96h 2.2 mg/l (rainbow trout) (OECD 203) <br />EC50 (48h) 3.27 mg/l (Daphnia (acute) toxicity) (OECD 202) <br />NOEC <br />1.2 mg/l /21d (Daphnia magna) (OECD 211) <br />0.04 mg/l /72h (Selenastrum capricornutum) (OECD 201) <br />0.21 mg/l /28d (rainbow trout) (OECD 215) <br />55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and <br />2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) <br />LC50 (48h) 0.16 mg/l (Daphnia magna) (vgl OECD 202) <br />LC50/96h 0.19 mg/l (rainbow trout) (vgl. OECD 203) <br />ERC50 <br />0.0052 mg/l (algae toxicity) (48h, OECD 201) <br />NOEC <br />0.1 mg/l (Daphnia magna) (21 d) <br />0.05 mg/l (rainbow trout) (14 d) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Endocrine disrupting properties <br />The product does not contain substances with endocrine disrupting properties. <br />(Contd. on page 7) <br />GB</p> <p>60.0.21</p> <p>Page 7/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 31.01.2025</p> <p>Version number 13 (replaces version 12)</p> <p>Revision: 31.01.2025</p> <p>Trade name: ASOPLAST-MZ <br />(Contd. of page 6)</p> <p>· 12.7 Other adverse effects <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water bodies or <br />sewage system. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />· Recommended cleaning agent: Water, if necessary with cleaning agent. <br />SECTION 14: Transport information <br />· 14.1 UN number or ID number <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant:</p> <p>No</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Maritime transport in bulk according to <br />IMO instruments <br />Not applicable. <br />· UN "Model Regulation":</p> <p>Void</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Poisons Act <br />· Regulated explosives precursors <br />None of the ingredients is listed. <br />· Regulated poisons <br />None of the ingredients is listed. <br />· Reportable explosives precursors <br />None of the ingredients is listed. <br />· Reportable poisons <br />None of the ingredients is listed. <br />(Contd. on page 8) <br />GB</p> <p>60.0.21</p> <p>Page 8/8</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 31.01.2025</p> <p>Version number 13 (replaces version 12)</p> <p>Revision: 31.01.2025</p> <p>Trade name: ASOPLAST-MZ <br />(Contd. of page 7)</p> <p>· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H301 <br />Toxic if swallowed. <br />H302 <br />Harmful if swallowed. <br />H310 <br />Fatal in contact with skin. <br />H314 <br />Causes severe skin burns and eye damage. <br />H315 <br />Causes skin irritation. <br />H317 <br />May cause an allergic skin reaction. <br />H318 <br />Causes serious eye damage. <br />H319 <br />Causes serious eye irritation. <br />H330 <br />Fatal if inhaled. <br />H400 <br />Very toxic to aquatic life. <br />H410 <br />Very toxic to aquatic life with long lasting effects. <br />EUH071 Corrosive to the respiratory tract. <br />· Department issuing data specification sheet: Environment protection department. <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />ATE: Acute toxicity estimate values <br />Acute Tox. 3: Acute toxicity – Category 3 <br />Acute Tox. 4: Acute toxicity – Category 4 <br />Acute Tox. 2: Acute toxicity – Category 2 <br />Skin Corr. 1C: Skin corrosion/irritation – Category 1C <br />Skin Irrit. 2: Skin corrosion/irritation – Category 2 <br />Eye Dam. 1: Serious eye damage/eye irritation – Category 1 <br />Skin Sens. 1: Skin sensitisation – Category 1 <br />Skin Sens. 1A: Skin sensitisation – Category 1A <br />Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 <br />Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1</p> <p>· * Data compared to the previous version altered. <br />GB</p>
