60.0.13
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Safety data sheet according to UK REACH Printing date 13.12.2024 *
Version number 30 (replaces version 29)
Revision: 13.12.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-SG2 (A-Komp.) · UFI: YEJC-NK0C-2009-68D5 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Epoxy coating · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS07 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS07 · Signal word Warning · Hazard-determining components of labelling: 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane Reaction products of hexane-1,6-diol with 2-(chloromethyl)oxirane (1:2) (Contd. on page 2) GB
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Safety data sheet according to UK REACH Printing date 13.12.2024
Trade name: ASODUR-SG2 (A-Komp.) (Contd. of page 1)
· Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · Additional information: EUH211 Warning! Hazardous respirable droplets may be formed when sprayed. Do not breathe spray or mist. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight 700. · Dangerous components: CAS: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)] 10-25% EINECS: 216-823-5 bisoxirane Index number: 603-073-00-2 Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 Specific concentration limits: Skin Irrit. 2; H315: C ≥ 5 % Eye Irrit. 2; H319: C ≥ 5 % CAS: 933999-84-9 EC number: 618-939-5
Reaction products of hexane-1,6-diol with 2-(chloromethyl) oxirane (1:2) Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; Aquatic Chronic 3, H412
CAS: 13463-67-7 titanium dioxide EINECS: 236-675-5 Carc. 2, H351 Index number: 022-006-00-2 · Additional information For the wording of the listed hazard phrases refer to section 16.
10-25%
2.5-10%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! (Contd. on page 3) GB
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Trade name: ASODUR-SG2 (A-Komp.) (Contd. of page 2)
· After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · For safety reasons unsuitable extinguishing agents Water with a full water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Not required. Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children (Contd. on page 4) GB
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Trade name: ASODUR-SG2 (A-Komp.) (Contd. of page 3)
· Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Store away from foodstuffs. Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 7727-43-7 barium sulphate, natural (25-50%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust · Regulatory information WEL: EH40/2020 · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures Wash hands during breaks and at the end of the work. The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination filter A2-P2 (brown/white) when spraying. · Hand protection Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min Nitrile rubber II R : thickness 0.425mm; breakthrough time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 5) GB
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Trade name: ASODUR-SG2 (A-Komp.) (Contd. of page 4)
· Not suitable are gloves made of the following materials: Leather gloves Strong gloves · Eye/face protection Suitable safety goggles in accordance with DIN EN 166. In case of splashing use protecting basket-glasses. · Body protection: Protective work clothing. Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: grey · Smell: Characteristic · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range Not determined · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: >100 °C · Decomposition temperature: Not determined. · pH Mixture is non-soluble (in water). · Viscosity: · Kinematic viscosity Not determined. · dynamic at 20 °C: 1,800 mPas · Solubility · Water: Not miscible or difficult to mix · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure: Not determined. · Density and/or relative density · Density at 20 °C 1.98 g/cm³ · Relative density Not determined. · Vapour density Not determined. · 9.2 Other information · Appearance: · Form: Fluid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent separation test · Organic solvents: 0.0 % · Solids content: 0.0 % · Change in condition · Evaporation rate Not determined. (Contd. on page 6) GB
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Trade name: ASODUR-SG2 (A-Komp.) (Contd. of page 5)
· Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 7727-43-7 barium sulphate, natural Oral LD50 >5,000 mg/kg (rats) (OECD 401) Dermal LD50 >2,000 mg/kg (rats) (read-across) 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane Oral LD50 >15,000 mg/kg (rats) Dermal LD50 23,000 mg/kg (Kan) 933999-84-9 Reaction products of hexane-1,6-diol with 2-(chloromethyl)oxirane (1:2) Oral LD50 2,190 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rabbit) 13463-67-7 titanium dioxide Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >10,000 mg/kg (rabbit) Inhalative LC50/4 h 6.8 mg/l (rats) (Contd. on page 7) GB
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Trade name: ASODUR-SG2 (A-Komp.) (Contd. of page 6)
64742-95-6 Solvent naphtha (petroleum), light arom. Oral LD50 6,800 mg/kg (rats) Dermal LD50 3,400 mg/kg (rabbit) Inhalative LC50/4 h 10.2 mg/l (rats) · Primary irritant effect: · Skin corrosion/irritation The product has an irritate-effect. Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause an allergic skin reaction. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane LC50/96h 2 mg/l (for) EC50 (48h) (static) 1.8 mg/l (Daphnia magna) ERC50 (static) 11 mg/l /72h (Scenedesmus capricornutum) IC50 >42.6 mg/l /18h (bacterial toxicity) 933999-84-9 Reaction products of hexane-1,6-diol with 2-(chloromethyl)oxirane (1:2) LC50/96h 30 mg/l (Leuciscus idus) EC50 (48h) 47 mg/l (Daphnia magna) 23.1 mg/l (algae toxicity) 13463-67-7 titanium dioxide LC 0 48 mg/l (Leuciscus idus) EC0 30 mg/l (Daphnia magna) 24 mg/l (Pseudomonas flourescens) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties For information on endocrine disrupting properties see section 11. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. GB
(Contd. on page 8)
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Trade name: ASODUR-SG2 (A-Komp.) (Contd. of page 7)
SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR
· IMDG
· IATA
UN3082 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average molecular weight<700)) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700)), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700))
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA): · 14.6 Special precautions for user · Kemler Number: · EMS Number: · Stowage Category
Product contains environmentally hazardous substances: bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700) Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles. 90 F-A,S-F A
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. (Contd. on page 9) GB
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Trade name: ASODUR-SG2 (A-Komp.) (Contd. of page 8)
· Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 3 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL A(EPICHLORHYDRIN); EPOXY RESIN(NUMBER AVERAGE MOLECULAR WEIGHT<700)), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · National regulations · Technical instructions (air): · Class Share in % · NK 0.5 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H351 Suspected of causing cancer. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. (Contd. on page 10) GB
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Trade name: ASODUR-SG2 (A-Komp.) (Contd. of page 9)
· Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Carc. 2: Carcinogenicity – Category 2 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB