SDS_ASODUR-K4031 (A-Komp.)_-_206409_(27)EN.pdf
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<h1>SDS_ASODUR-K4031 (A-Komp.)_-_206409_(27)EN.pdf</h1> <p>59.1.3</p> <p>Page 1/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 24.07.2024 <br />*</p> <p>Version number 27 (replaces version 26)</p> <p>Revision: 24.07.2024</p> <p>SECTION 1: Identification of the substance/mixture and of the company/undertaking <br />· 1.1 Product identifier <br />· Trade name: ASODUR-K4031 (A-Komp.) <br />· UFI: JND0-K07D-Q00U-29FK <br />· 1.2 Relevant identified uses of the substance or mixture and uses advised against <br />No further relevant information available. <br />· Application of the substance / the mixture Epoxy resin adhesive <br />· 1.3 Details of the supplier of the safety data sheet <br />· Manufacturer/Supplier: <br />SCHOMBURG GmbH & Co. KG <br />Aquafinstr. 2-8 <br />D-32760 Detmold <br />Detmold, Germany <br />---------------------------------------------Tel: ++49 (0)5231/953-00 <br />Fax: ++49 (0)5231/953-123 <br />Internet: www.schomburg.de <br />· Informing department: <br />Department: Environment and Safety <br />************************************ <br />If you have any questions about the Environment and Safety Department, please contact our <br />department. <br />e-mail: SDB@schomburg.de</p> <p>*</p> <p>SECTION 2: Hazards identification <br />· 2.1 Classification of the substance or mixture <br />· Classification according to Regulation (EC) No 1272/2008 <br />health hazard <br />Repr. 1B</p> <p>H360F May damage fertility.</p> <p>Skin Irrit. 2 <br />Eye Irrit. 2 <br />Skin Sens. 1</p> <p>H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H317 May cause an allergic skin reaction.</p> <p>Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. <br />· 2.2 Label elements <br />· Labelling according to Regulation (EC) No 1272/2008 <br />The product is classified and labelled according to the GB CLP regulation. <br />· Hazard pictograms GHS07, GHS08 <br />· Signal word Danger <br />· Hazard-determining components of labelling: <br />2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane <br />oxirane, mono[(C12-14-alkyloxy)methyl] derivs <br />(Contd. on page 2) <br />GB</p> <p>59.1.3</p> <p>Page 2/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 24.07.2024</p> <p>Version number 27 (replaces version 26)</p> <p>Revision: 24.07.2024</p> <p>Trade name: ASODUR-K4031 (A-Komp.) <br />(Contd. of page 1)</p> <p>Epoxy Phenol Novolak Resin <br />· Hazard statements <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H317 May cause an allergic skin reaction. <br />H360F May damage fertility. <br />H412 Harmful to aquatic life with long lasting effects. <br />· Precautionary statements <br />P261 <br />Avoid breathing dust/fume/gas/mist/vapours/spray. <br />P273 <br />Avoid release to the environment. <br />P280 <br />Wear protective gloves/protective clothing/eye protection/face protection/hearing <br />protection. <br />P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />P405 <br />Store locked up. <br />P501 <br />Dispose of contents/container in accordance with local/regional/national/ <br />international regulations. <br />· 2.3 Other hazards <br />· Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />SECTION 3: Composition/information on ingredients <br />· 3.2 Mixtures <br />· Description: Mixture of substances listed below and non-hazardous additions. <br />· Dangerous components: <br />10-25% <br />CAS: 1675-54-3 <br />2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)] <br />EINECS: 216-823-5 <br />bisoxirane <br />Index number: 603-073-00-2 <br />Aquatic Chronic 2, H411; <br />Skin Irrit. 2, H315; Eye Irrit. 2, <br />H319; Skin Sens. 1, H317 <br />Specific concentration limits: Skin Irrit. 2; H315: C ≥ 5 % <br />Eye Irrit. 2; H319: C ≥ 5 % <br />EC number: 701-263-0</p> <p>Epoxy Phenol Novolak Resin <br />Aquatic Chronic 2, H411; <br />1, H317</p> <p>2.5-10% <br />Skin Irrit. 2, H315; Skin Sens.</p> <p>CAS: 68609-97-2 <br />oxirane, mono[(C12-14-alkyloxy)methyl] derivs <br />EINECS: 271-846-8 <br />Repr. 1B, H360F; <br />Skin Irrit. 2, H315; Skin Sens. 1, <br />Index number: 603-103-00-4 H317, EUH205</p> <p>2.5-10%</p> <p>CAS: 13463-67-7 <br />titanium dioxide <br />EINECS: 236-675-5 <br />Carc. 2, H351 <br />Index number: 022-006-00-2 <br />· Additional information For the wording of the listed hazard phrases refer to section 16.</p> <p><1%</p> <p>SECTION 4: First aid measures <br />· 4.1 Description of first aid measures <br />· General information <br />Symptoms of poisoning may even occur after several hours; therefore medical observation for at <br />least 48 hours after the accident. <br />Personal protection for the First Aider. <br />It is possible to choke in case of vomiting in unconsciousness. <br />Bring unconscious persons into a stable position on side. <br />Keep the respiratory tract free (remove dentures and vomiting). <br />Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage <br />of breathing: artificial respiration. <br />(Contd. on page 3) <br />GB</p> <p>59.1.3</p> <p>Page 3/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 24.07.2024</p> <p>Version number 27 (replaces version 26)</p> <p>Revision: 24.07.2024</p> <p>Trade name: ASODUR-K4031 (A-Komp.) <br />(Contd. of page 2)</p> <p>Take up a doctor immediately! <br />· After inhalation <br />Supply fresh air or oxygen; call for doctor. <br />In case of unconsciousness bring patient into stable side position for transport. <br />Supply fresh air and call for doctor for safety reasons. <br />· After skin contact <br />In case of contact with skin, remove mechanically, wash thoroughly with plenty of soap and water. <br />Instantly wash with water and soap and rinse thoroughly. <br />Change immediately contaminated clothes. <br />· After eye contact <br />Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. <br />· After swallowing <br />Drink copious amounts of water and provide fresh air. Instantly call for doctor. <br />Do not induce vomiting; instantly call for medical help. <br />Show the packaging or the label to the doctor. <br />· 4.2 Most important symptoms and effects, both acute and delayed <br />No further relevant information available. <br />· 4.3 Indication of any immediate medical attention and special treatment needed <br />No further relevant information available. <br />SECTION 5: Firefighting measures <br />· 5.1 Extinguishing media <br />· Suitable extinguishing agents <br />CO2, extinguishing powder or water jet. Fight larger fires with water jet. <br />· 5.2 Special hazards arising from the substance or mixture <br />Formation of poisonous gases during heating or in fires. <br />· 5.3 Advice for firefighters <br />· Protective equipment: Wear self-contained breathing apparatus. <br />· Additional information <br />Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. <br />Follow the emergency-plan. <br />SECTION 6: Accidental release measures <br />· 6.1 Personal precautions, protective equipment and emergency procedures <br />Bring persons out of danger. <br />Wear protective equipment. Keep unprotected persons away. <br />· 6.2 Environmental precautions: <br />Do not allow product to reach sewage system or water bodies. <br />Inform respective authorities in case product reaches water or sewage system. <br />· 6.3 Methods and material for containment and cleaning up: <br />Pick up the product mechanically, avoid dust formation. <br />· 6.4 Reference to other sections <br />See Section 7 for information on safe handling <br />See Section 8 for information on personal protection equipment. <br />See Section 13 for information on disposal. <br />SECTION 7: Handling and storage <br />· 7.1 Precautions for safe handling <br />Prevent formation of dust. <br />Keep out of the reach of children <br />· Information about protection against explosions and fires: No special measures required. <br />(Contd. on page 4) <br />GB</p> <p>59.1.3</p> <p>Page 4/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 24.07.2024</p> <p>Version number 27 (replaces version 26)</p> <p>Revision: 24.07.2024</p> <p>Trade name: ASODUR-K4031 (A-Komp.) <br />(Contd. of page 3)</p> <p>· 7.2 Conditions for safe storage, including any incompatibilities <br />· Storage <br />· Requirements to be met by storerooms and containers: No special requirements. <br />· Information about storage in one common storage facility: <br />Please follow the rules of the VCI-Storage-Concept for chemicals. <br />· Further information about storage conditions: Keep container tightly sealed. <br />· 7.3 Specific end use(s) No further relevant information available. <br />*</p> <p>SECTION 8: Exposure controls/personal protection <br />· 8.1 Control parameters <br />· Components with critical values that require monitoring at the workplace: <br />1317-65-3 Calciumcarbonat (10-25%) <br />WEL Long-term value: 10* 4** mg/m³ <br />*inhalable dust; **respirable <br />13463-67-7 titanium dioxide (<1%) <br />WEL Long-term value: 10* 4** mg/m³ <br />*total inhalable **respirable <br />· Additional information: The lists that were valid during the compilation were used as basis. <br />· 8.2 Exposure controls <br />· Appropriate engineering controls <br />It must be possible to wash the skin in the working area. <br />Eye-wash bottle must be available. <br />· Individual protection measures, such as personal protective equipment <br />· General protective and hygienic measures <br />The usual precautionary measures should be adhered to in handling the chemicals. <br />Keep away from foodstuffs, beverages and food. <br />Instantly remove any soiled and impregnated garments. <br />Vacuum clean contaminated clothing. Do not blow or brush off contamination. <br />Avoid contact with the eyes and skin. <br />Do not eat, drink or smoke while working. <br />Use skin protection cream for preventive skin protection. <br />Be sure to clean skin thoroughly after work and before breaks. <br />· Breathing equipment: <br />Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination <br />filter A2-P2 (brown/white) when spraying. <br />· Hand protection <br />Treat all uncovered body parts with fat-free or low-fat (oil in water emulsion) skin protection cream. <br />Hand Protection: Nitril-rubber-latex-gloves. <br />In case of wearing synthetic protective gloves use cotton-gloves as underwear. <br />The glove material has to be impermeable and resistant to the product/ the substance/ the <br />preparation. <br />Selection of the glove material on consideration of the penetration times, rates of diffusion and the <br />degradation <br />· Material of gloves <br />Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min <br />Nitrile rubber II R : thickness 0.425mm; breakthrough time 480 min <br />The selection of the suitable gloves does not only depend on the material, but also on further marks <br />of quality and varies from manufacturer to manufacturer. As the product is a preparation of several <br />substances, the resistance of the glove material can not be calculated in advance and has therefore <br />to be checked prior to the application. <br />· Penetration time of glove material <br />The exact break trough time has to be found out by the manufacturer of the protective gloves and <br />has to be observed. <br />· Eye/face protection Suitable eye protection: Basket goggles. (DIN EN 166) <br />(Contd. on page 5) <br />GB</p> <p>59.1.3</p> <p>Page 5/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 24.07.2024</p> <p>Version number 27 (replaces version 26)</p> <p>Revision: 24.07.2024</p> <p>Trade name: ASODUR-K4031 (A-Komp.) <br />(Contd. of page 4)</p> <p>· Body protection: <br />Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. <br />Contaminated protection clothes must be cleaned carefully before reuse. <br />SECTION 9: Physical and chemical properties <br />· 9.1 Information on basic physical and chemical properties <br />· General Information <br />· Physical state <br />Solid material. <br />· Colour: <br />grey <br />· Smell: <br />Characteristic <br />· Odour threshold: <br />Not determined. <br />· Melting point/freezing point: <br />Not determined <br />· Boiling point or initial boiling point and <br />boiling range <br />not apply <br />· Flammability <br />Not determined. <br />· Lower and upper explosion limit <br />· Lower: <br />Not determined. <br />· Upper: <br />Not determined. <br />· Flash point: <br />Not applicable <br />· Decomposition temperature: <br />Not determined. <br />· pH <br />Mixture is non-soluble (in water). <br />· Viscosity: <br />· Kinematic viscosity <br />Not applicable. <br />· dynamic: <br />Not applicable. <br />· Solubility <br />· Water: <br />not miscible <br />· Partition coefficient n-octanol/water (log <br />value) <br />Not determined. <br />· Steam pressure: <br />Not applicable. <br />· Density and/or relative density <br />· Density at 20 °C <br />1.4 g/cm³ <br />bulk density <br />· Relative density <br />Not determined. <br />· Vapour density <br />Not applicable. <br />· 9.2 Other information <br />· Appearance: <br />· Form: <br />Pasty <br />· Important information on protection of health <br />and environment, and on safety. <br />· Self-inflammability: <br />Product is not selfigniting. <br />· Explosive properties: <br />Product is not explosive. <br />· Solvent content: <br />· Organic solvents: <br />0.1 % <br />· Change in condition <br />· Evaporation rate <br />Not applicable. <br />· Information with regard to physical hazard <br />classes <br />· Explosives <br />· Flammable gases <br />· Aerosols <br />· Oxidising gases <br />· Gases under pressure <br />· Flammable liquids <br />· Flammable solids</p> <p>Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />(Contd. on page 6) <br />GB</p> <p>59.1.3</p> <p>Page 6/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 24.07.2024</p> <p>Version number 27 (replaces version 26)</p> <p>Revision: 24.07.2024</p> <p>Trade name: ASODUR-K4031 (A-Komp.) <br />(Contd. of page 5)</p> <p>· Self-reactive substances and mixtures <br />· Pyrophoric liquids <br />· Pyrophoric solids <br />· Self-heating substances and mixtures <br />· Substances and mixtures, which emit <br />flammable gases in contact with water <br />· Oxidising liquids <br />· Oxidising solids <br />· Organic peroxides <br />· Corrosive to metals <br />· Desensitised explosives</p> <p>Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void <br />Void</p> <p>SECTION 10: Stability and reactivity <br />· 10.1 Reactivity No further relevant information available. <br />· 10.2 Chemical stability <br />· Thermal decomposition / conditions to be avoided: <br />No decomposition if used according to specifications. <br />· 10.3 Possibility of hazardous reactions Reacts with strong acids and oxidizing agents <br />· 10.4 Conditions to avoid No further relevant information available. <br />· 10.5 Incompatible materials: No further relevant information available. <br />· 10.6 Hazardous decomposition products: No dangerous decomposition products known <br />SECTION 11: Toxicological information <br />· 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 <br />· Acute toxicity Based on available data, the classification criteria are not met. <br />· LD/LC50 values that are relevant for classification: <br />1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane <br />Oral <br />LD50 <br />>15,000 mg/kg (rats) <br />Dermal LD50 <br />23,000 mg/kg (Kan) <br />Epoxy Phenol Novolak Resin <br />Oral <br />LD50 <br />>5,000 mg/kg (rats) (OECD 401) <br />Dermal LD50 <br />>2,000 mg/kg (rats) (OECD 402) <br />68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs <br />Oral <br />LD50 <br />>5,000 mg/kg (rats) <br />Dermal LD50 <br />>4,500 mg/kg (rabbit) <br />13463-67-7 titanium dioxide <br />Oral <br />LD50 <br />>5,000 mg/kg (rats) <br />Dermal LD50 <br />>10,000 mg/kg (rabbit) <br />Inhalative LC50/4 h 6.8 mg/l (rats) <br />· Skin corrosion/irritation <br />The product has an irritate-effect. <br />Causes skin irritation. <br />· Serious eye damage/irritation Causes serious eye irritation. <br />· Respiratory or skin sensitisation May cause an allergic skin reaction. <br />· Reproductive toxicity May damage fertility. <br />· Additional toxicological information: Sensitizing <br />(Contd. on page 7) <br />GB</p> <p>59.1.3</p> <p>Page 7/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 24.07.2024</p> <p>Version number 27 (replaces version 26)</p> <p>Revision: 24.07.2024</p> <p>Trade name: ASODUR-K4031 (A-Komp.) <br />(Contd. of page 6)</p> <p>· 11.2 Information on other hazards <br />· Endocrine disrupting properties <br />None of the ingredients is listed. <br />SECTION 12: Ecological information <br />· 12.1 Toxicity <br />· Aquatic toxicity: <br />1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane <br />LC50/96h <br />2 mg/l (for) <br />EC50 (48h) (static) 1.8 mg/l (Daphnia magna) <br />ERC50 (static) <br />11 mg/l /72h (Scenedesmus capricornutum) <br />IC50 <br />>42.6 mg/l /18h (bacterial toxicity) <br />Epoxy Phenol Novolak Resin <br />LC50/96h <br />5.7 mg/l (Leuciscus idus) <br />EC50 (48h) <br />2.55 mg/l (Daphnia magna) <br />EC50 <br />1.8 mg/l (Selenastrum capricornutum) (OECD 201) <br />IC50 (static) <br />>100 mg/l /3h (activated sludge bacteria) <br />68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs <br />LC50/96h <br />>5,000 mg/l (rainbow trout) <br />EC50 (48h) (static) 7.2 mg/l (Daphnia magna) (OECD 202) <br />EC/LC50 (72h) <br />844 mg/l (algae toxicity) <br />IC50 (static) <br />>100 mg/l /3h (activated sludge bacteria) (OECD 209) <br />NOEC <br />500 mg/l /72h (Pseudokirchneriella subcapitata) <br />13463-67-7 titanium dioxide <br />LC 0 <br />48 mg/l (Leuciscus idus) <br />EC0 <br />30 mg/l (Daphnia magna) <br />24 mg/l (Pseudomonas flourescens) <br />· 12.2 Persistence and degradability No further relevant information available. <br />· 12.3 Bioaccumulative potential No further relevant information available. <br />· 12.4 Mobility in soil No further relevant information available. <br />· 12.5 Results of PBT and vPvB assessment <br />· PBT: Not applicable. <br />· vPvB: Not applicable. <br />· 12.6 Endocrine disrupting properties <br />For information on endocrine disrupting properties see section 11. <br />· 12.7 Other adverse effects <br />· Additional ecological information: <br />· General notes: <br />Water hazard class 2 (Self-assessment): hazardous for water. <br />Do not allow product to reach ground water, water bodies or sewage system. <br />Danger to drinking water if even small quantities leak into soil. <br />SECTION 13: Disposal considerations <br />· 13.1 Waste treatment methods <br />· Recommendation <br />Must not be disposed of together with household garbage. Do not allow product to reach sewage <br />system. <br />(Contd. on page 8) <br />GB</p> <p>59.1.3</p> <p>Page 8/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 24.07.2024</p> <p>Version number 27 (replaces version 26)</p> <p>Revision: 24.07.2024</p> <p>Trade name: ASODUR-K4031 (A-Komp.) <br />(Contd. of page 7)</p> <p>· Uncleaned packagings: <br />· Recommendation: Disposal must be made according to official regulations. <br />SECTION 14: Transport information <br />· 14.1 UN number or ID number <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.2 UN proper shipping name <br />· ADR, ADN, IMDG, IATA</p> <p>Void</p> <p>· 14.3 Transport hazard class(es) <br />· ADR, ADN, IMDG, IATA <br />· Class</p> <p>Void</p> <p>· 14.4 Packing group <br />· ADR, IMDG, IATA</p> <p>Void</p> <p>· 14.5 Environmental hazards: <br />· Marine pollutant:</p> <p>No</p> <p>· 14.6 Special precautions for user</p> <p>Not applicable.</p> <p>· 14.7 Maritime transport in bulk according to <br />IMO instruments <br />Not applicable. <br />· UN "Model Regulation":</p> <p>Void</p> <p>SECTION 15: Regulatory information <br />· 15.1 Safety, health and environmental regulations/legislation specific for the substance or <br />mixture <br />· Poisons Act <br />· Regulated explosives precursors <br />None of the ingredients is listed. <br />· Regulated poisons <br />None of the ingredients is listed. <br />· Reportable explosives precursors <br />None of the ingredients is listed. <br />· Reportable poisons <br />None of the ingredients is listed. <br />· Directive 2012/18/EU <br />· Named dangerous substances - ANNEX I None of the ingredients is listed. <br />· National regulations <br />· Technical instructions (air): <br />· Class Share in % <br />· NK <br />0.1 <br />· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />SECTION 16: Other information <br />These data are based on our present knowledge. However, they shall not constitute a guarantee for <br />any specific product features and shall not establish a legally valid contractual relationship. <br />· Relevant phrases <br />H315 <br />Causes skin irritation. <br />(Contd. on page 9) <br />GB</p> <p>59.1.3</p> <p>Page 9/9</p> <p>Safety data sheet <br />according to UK REACH <br />Printing date 24.07.2024</p> <p>Version number 27 (replaces version 26)</p> <p>Revision: 24.07.2024</p> <p>Trade name: ASODUR-K4031 (A-Komp.) <br />(Contd. of page 8)</p> <p>H317 <br />May cause an allergic skin reaction. <br />H319 <br />Causes serious eye irritation. <br />H351 <br />Suspected of causing cancer. <br />H360F May damage fertility. <br />H411 <br />Toxic to aquatic life with long lasting effects. <br />EUH205 Contains epoxy constituents. May produce an allergic reaction. <br />· Department issuing data specification sheet: Environment protection department. <br />· Contact: <br />Environment protection department. <br />Mr. Guido Herfort <br />· Abbreviations and acronyms: <br />ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning <br />the International Carriage of Dangerous Goods by Road) <br />IMDG: International Maritime Code for Dangerous Goods <br />IATA: International Air Transport Association <br />GHS: Globally Harmonised System of Classification and Labelling of Chemicals <br />EINECS: European Inventory of Existing Commercial Chemical Substances <br />ELINCS: European List of Notified Chemical Substances <br />CAS: Chemical Abstracts Service (division of the American Chemical Society) <br />LC50: Lethal concentration, 50 percent <br />LD50: Lethal dose, 50 percent <br />PBT: Persistent, Bioaccumulative and Toxic <br />vPvB: very Persistent and very Bioaccumulative <br />Skin Irrit. 2: Skin corrosion/irritation – Category 2 <br />Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 <br />Skin Sens. 1: Skin sensitisation – Category 1 <br />Carc. 2: Carcinogenicity – Category 2 <br />Repr. 1B: Reproductive toxicity – Category 1B <br />Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 <br />Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3</p> <p>· * Data compared to the previous version altered. <br />GB</p>
