60.0.21
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Safety data sheet according to UK REACH Printing date 14.01.2025
Version number 22 (replaces version 21)
Revision: 14.01.2025
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-EV200 (A-Komp.) · UFI: 8FQE-XK2D-800S-TVGJ · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Bonded Epoxy resin bottom casting mortar · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS07, GHS09 · Signal word Warning (Contd. on page 2) GB
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Trade name: ASODUR-EV200 (A-Komp.) (Contd. of page 1)
· Hazard-determining components of labelling: 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane Reaction products of hexane-1,6-diol with 2-(chloromethyl)oxirane (1:2) Bisphenol F epoxy resin benzyl alcohol · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Solvent- free preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight 700. · Dangerous components: CAS: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)] 50-100% EINECS: 216-823-5 bisoxirane Index number: 603-073-00-2 Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 Specific concentration limits: Skin Irrit. 2; H315: C ≥ 5 % Eye Irrit. 2; H319: C ≥ 5 % CAS: 933999-84-9 EC number: 618-939-5
Reaction products of hexane-1,6-diol with 2-(chloromethyl) oxirane (1:2) Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; Aquatic Chronic 3, H412
10-25%
CAS: 9003-36-5 NLP: 500-006-8
Bisphenol F epoxy resin Aquatic Chronic 2, H411; 1, H317
2.5-10% Skin Irrit. 2, H315; Skin Sens.
CAS: 100-51-6 benzyl alcohol EINECS: 202-859-9 Acute Tox. 4, H302; Acute Tox. 4, H332; Eye Irrit. 2, Index number: 603-057-00-5 H319; Skin Sens. 1B, H317 ATE: LD50 oral: 1,200 mg/kg · Additional information Contains epoxide-compounds. Note the index of the manufacturer. For the wording of the listed hazard phrases refer to section 16.
2.5-10%
GB
(Contd. on page 3)
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Trade name: ASODUR-EV200 (A-Komp.) (Contd. of page 2)
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Don't use solvents to clean the skin. Instantly wash with water and soap and rinse thoroughly. Instantly rinse with water. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Avoid eye- and skin contact. Do not breath in vapour. Keep away from ignition sources Bring persons out of danger. (Contd. on page 4) GB
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Trade name: ASODUR-EV200 (A-Komp.) (Contd. of page 3)
Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding, inflammable material (sand, diatomite, acid binders, universal binder). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep containers tightly sealed. Work with fresh air supply (open windows and doors). Keep away from heat and direct sunlight. Avoid splashes. Do not spray on hot surfaces. Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Do not leave open containers. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Protect from frost. Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures Clean skin only with cleaning agent especially for epoxy resin. Don't use solvent for skin cleaning! Clean clothes which are contaminate with epoxi resin before unsing again. Wash hands during breaks and at the end of the work. The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. (Contd. on page 5) GB
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Trade name: ASODUR-EV200 (A-Komp.) (Contd. of page 4)
Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination filter A2-P2 (brown/white) when spraying. · Hand protection Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves Strong gloves · Eye/face protection Tightly sealed safety glasses. Suitable safety goggles in accordance with DIN EN 166. · Body protection: Protective work clothing. Contaminated protection clothes must be cleaned carefully before reuse. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Liquid · Colour: Colourless · Smell: Weak, characteristic · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range Not determined · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: Not applicable · Decomposition temperature: Not determined. · pH Mixture is non-soluble (in water). · Viscosity: · Kinematic viscosity Not determined. · dynamic: Not determined. · Solubility · Water: Not miscible or difficult to mix · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure: Not determined. (Contd. on page 6) GB
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Trade name: ASODUR-EV200 (A-Komp.) (Contd. of page 5)
· Density and/or relative density · Density at 20 °C · Relative density · Vapour density
1.14 g/cm³ Not determined. Not determined.
· 9.2 Other information · Appearance: · Form: Liquid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent separation test · Organic solvents: ≥0.3-<0.4 % · Solids content: 0.0 % · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts violently with oxidizing agents · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: Can react with acid and oxidizing agents. · 10.6 Hazardous decomposition products: În case of heating dangerous decomposition products can be arise. SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. (Contd. on page 7) GB
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Trade name: ASODUR-EV200 (A-Komp.) (Contd. of page 6)
· LD/LC50 values that are relevant for classification: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane Oral LD50 >15,000 mg/kg (rats) Dermal LD50 23,000 mg/kg (Kan) 933999-84-9 Reaction products of hexane-1,6-diol with 2-(chloromethyl)oxirane (1:2) Oral LD50 2,190 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rabbit) 9003-36-5 Bisphenol F epoxy resin Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rats) 100-51-6 benzyl alcohol Oral LD50 1,200 mg/kg (ATE) 1,040 mg/kg (mouse) 1,620 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rabbit) Inhalative LC50 4.178 mg/l (rats) (OECD 403) · Primary irritant effect: · Skin corrosion/irritation The product has an irritate-effect. Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. · Respiratory or skin sensitisation May cause an allergic skin reaction. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 1675-54-3 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane LC50/96h 2 mg/l (for) EC50 (48h) (static) 1.8 mg/l (Daphnia magna) ERC50 (static) 11 mg/l /72h (Scenedesmus capricornutum) IC50 >42.6 mg/l /18h (bacterial toxicity) 933999-84-9 Reaction products of hexane-1,6-diol with 2-(chloromethyl)oxirane (1:2) LC50/96h 30 mg/l (Leuciscus idus) EC50 (48h) 47 mg/l (Daphnia magna) 23.1 mg/l (algae toxicity) 9003-36-5 Bisphenol F epoxy resin LC50/96h 2.54 mg/l (fish toxicity) EC50 (48h) 2.55 mg/l (Daphnia magna) EC/LC50 (72h) 1.8 mg/l (algae toxicity) 100-51-6 benzyl alcohol EC 50 390 mg/kg /(24h) (Pseudomas putida) LC50/96h 460 mg/l (Pimephales promelas) (EPA OPP 72-1) 645 mg/l (orfe) (Contd. on page 8) GB
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Trade name: ASODUR-EV200 (A-Komp.) (Contd. of page 7)
EC10 >658 mg/l /16h (Pseudomas putida) (DIN 38412) EC50 (48h) 230 mg/l (Daphnia magna) (OECD 202) EC/LC50 (72h) (static) 770 mg/l (Pseudokirchneriella subcapitata) (OECD 201) NOEC 51 mg/l /21d (Daphnia magna) (OECD 211) 310 mg/l (Pseudokirchneriella subcapitata) (OECD 201) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Remark: Harmful to fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. Harmful to aquatic organisms SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Empty Containers with solid product rests can be supplied for recycling. Empty Containers including fluid product rests are hazardous waste. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR
· IMDG
· IATA
UN3082 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A(epichlorhydrin); epoxy resin(number average molecular weight<700), Bisphenol F epoxy resin) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700), Bisphenol F epoxy resin), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number average molecular weight<700), Bisphenol F epoxy resin) (Contd. on page 9) GB
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Trade name: ASODUR-EV200 (A-Komp.) (Contd. of page 8)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA): · 14.6 Special precautions for user · Kemler Number: · EMS Number: · Stowage Category
Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles. 90 F-A,S-F A
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 3 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL A(EPICHLORHYDRIN); EPOXY RESIN(NUMBER AVERAGE MOLECULAR WEIGHT<700), BISPHENOL F EPOXY RESIN), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. (Contd. on page 10) GB
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Trade name: ASODUR-EV200 (A-Komp.) (Contd. of page 9)
· Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Seveso category E2 Hazardous to the Aquatic Environment · Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t · National regulations · Technical instructions (air): · Class Share in % · NK 0.5 · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative ATE: Acute toxicity estimate values Acute Tox. 4: Acute toxicity – Category 4 Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1B: Skin sensitisation – Category 1B Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB